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951.
952.
953.
We introduce a generalized notion of semiring and prove that all known properties that semirings have according to the old definition are preserved. 相似文献
954.
In this work we consider computing and continuing connecting orbits in parameter dependent dynamical systems. We give details
of algorithms for computing connections between equilibria and periodic orbits, and between periodic orbits. The theoretical
foundation for these techniques is given by the seminal work of Beyn in 1994, “On well-posed problems for connecting orbits
in dynamical systems”, where a numerical technique is also proposed. Our algorithms consist of splitting the computation of
the connection from that of the periodic orbit(s). To set up appropriate boundary conditions, we follow the algorithmic approach
used by Demmel, Dieci, and Friedman, for the case of connecting orbits between equilibria, and we construct and exploit the
smooth block Schur decomposition of the monodromy matrices associated to the periodic orbits. Numerical examples illustrate
the performance of the algorithms.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
955.
The enthalpies and free energies of proton affinity (PA) were calculated by the PM3 method for 27 thiophenoxide anions. For thiophenols, linear correlation has been found between the PAs and the values of pK
a
measured by different authors in aqueous acetone, aqueous ethanol, and methanol media. The dependences found permit one to predict a priori the protolytic properties of thiophenols. The differential effects of aqueous ethanol media with different ethanol contents on thiophenol acidity were evaluated based on quantum-chemical data.Original Russian Text Copyright © 2004 by A. N. Pankratov and A. V. Shalabai__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 800–806, September–October, 2004. 相似文献
956.
全变差有界函数列的一致(R)可积性 总被引:4,自引:0,他引:4
给出了一致有界单调函数列一致可积性定理 ,由此得出全变差序列有界的收敛函数列的一致可积性 .说明了该结论可判断一些非一致收敛函数列的逐项积分性质 . 相似文献
957.
958.
A. V. Tarasov P. O. Yablonsky Yu. A. Moskvichev 《Chemistry of Heterocyclic Compounds》2003,39(1):119-122
Various methods were studied for the oxidation of 2-methyl-5-(phenylsulfonyl)benzenesulfamide and its derivatives. The oxidation by sodium dichromate in sulfuric acid was found most efficient. The effects of temperature, concentration, reagent ratio, and time of the oxidation reaction on the yield of the desired product were investigated. Conditions were proposed for obtaining the desired product in yields up to 95%. A synthesis was developed for a series of new saccharin derivatives. 相似文献
959.
960.
On the basis of critical comparison of experimental and theoretical values of the E parameter and investigation of the retardation effect of oxygen on the evaporation rate of ZnO, CdO and HgO, it was concluded that the dissociative evaporation of ZnO and HgO proceeds with releasing of atomic oxygen (O) as a primary product of decomposition. By contrast, the mechanism of dissociative evaporation of CdO corresponds to the equilibrium reaction with releasing of molecular oxygen (O2) as a primary product of decomposition. As was shown, this difference in mechanisms is not related with interatomic OO distances in these oxides. From the analysis of crystal structure for 12 different oxides, which evaporate with releasing of atomic oxygen, and for 13 compounds, which evaporate with releasing of molecular oxygen, it was revealed that the first mechanism is observed for all oxides with the cubic crystal structure. It was proposed that a decisive role in this difference belongs to a local symmetry in the position of O atoms. 相似文献